PEOPLE.COM Launches Sexiest Man and Woman on TV Poll; To Be Announced During EMMYS Red Carpet

People.com is launching its first-ever Sexiest Man and Woman on TV poll. Users will have the opportunity to vote for their favorite of five male and five female finalists chosen by PEOPLE's editorial staff. Voting begins today on www.people.com, www.emmys.com and www.abc.com, and will continue until 7:30 p.m., ET / 4:30 p.m., PT on Sunday, September 23, the evening of "The 64th Primetime Emmy® Awards."

The five male TV star finalists are LL Cool J ("NCIS: Los Angeles"), Jon Hamm ("Mad Men"), Joe Manganiello ("True Blood"), Dylan McDermott ("American Horror Story") and Aa Ron Paul ("Breaking Bad"). The five female TV star finalists are Zooey Deschanel ("New Girl"), Christina Hendricks ("Mad Men"), Heidi Klum ("Project Runway"), Sofía Vergara ("Modern Family") and Kerry Washington ("Scandal").

The winners of the poll will be announced live on ABC's "Emmys Red Carpet Live," hosted by "Good Morning America's" Josh Elliott & Lara Spencer, CHRIS HARRISON ("The Bachelor" / "The Bachelorette") and Clinton Kelly ("The Chew," "What Not to Wear"), which begins the festivities of TV's biggest night, coast to coast, SUNDAY, SEPTEMBER 23 from 7:00-8:00 p.m., ET / 4:00-5:00 p.m., PT, immediately followed by the awards ceremonies, live from 8:00-11:00 p.m., ET / 5:00-8:00 p.m., PT. Jimmy Kimmel, star and executive producer of the late-night ABC talk show, "Jimmy Kimmel Live," hosts "The 64th Primetime Emmy Awards."